Synthesis of Trimeric Organozinc Compounds and their Subsequent Reaction with Oxygen
نویسندگان
چکیده
منابع مشابه
Synthesis of Trimeric Organozinc Compounds and their Subsequent Reaction with Oxygen
A conventional solution-based route to a cyclic trimeric organozinc compound [{Zn(Et)(β-diketonate)}3] (β-diketonate=OC(OMe)CHC(Me)O, 1) is described, with 1 structurally characterized for the first time. The ligand selection of bidentate β-diketonates is shown to be key to isolating a cyclic trimer. Additional reaction of β-diketonates with diethyl zinc were spectroscopically characterized as ...
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A review of the present state of organozinc coordination chemistry. with special emphasis on compounds of the type RZnX is given. Their preparation as well as some factors determining their structure and stability are discussed. Certain organozinc coordination compounds have been found to be effective catalysts for cyclo-oligomerization and polymerization reactions. in particular of oxygen-cont...
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ژورنال
عنوان ژورنال: ChemistryOpen
سال: 2016
ISSN: 2191-1363
DOI: 10.1002/open.201600040